Oops
Sunday, February 23rd, 2003Ric Pashley, an Australian chemist, has demonstrated that oil and water can mix.
If confirmed, the finding could provide clues to one of chemistry’s most puzzling phenomena. This is the so-called long-range hydrophobic force, which causes oil surfaces to attract one another over what to chemists are remarkably long distances.
Effectively, Pashley’s claim is that dissolved gas is necessary for the action of the so-called long-range hydrophobic force. In the absence of dissovled gas, water and oil spontaneously mixed. (Unfortunately, the summary article doesn’t say how hard they were pumping.)
Although this is exciting for physical chemists, and in a distant way interesting to biologists (after all, there are very few biology samples that you can repeatedly freeze and evacuate), it’s earth-shattering for theoretical chemists.
Any simulation that purported to show spontaneous separation of oil and water is now known to be garbage. The paper-and-pencil crowd will have to figure out how to work dissolved gas into their models. If Pashley is right (his results haven’t yet been reproduced), it means that we have to throw away most of our liquid theories.
It almost makes me wish I were back in grad school, doing liquid theory, for the chance to work on these problems in a relatively clear field. Unfortunately, the other structural problems of theoretical chemistry remain: low relevance and intractable computing problems.
And although accounting for dissolved gas is now known to be necessary, there’s nothing to say that it’s the last factor that needs to be accounted for in theory. Very likely it’s not. Water is messy stuff, full of dissolved ions, gases, small organic molecules, and we’re not really very good at modeling it.